Thiazolylidene-Catalysed Cleavage of Methyl Oleate-Derived α-Hydroxyketone to the Corresponding Free Aldehydes
Résumé
Thiazolylidene-catalysed cleavage of the α-hydroxyketone derived from methyl oleate gave the corresponding aldehydes under non-oxidative conditions through a retro-benzoin process. The aldehydes produced are in equilibrium with their corresponding acyloins. To illustrate the synthetic utility of this protocol, the aldehydes were recovered by distillation.
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