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Article Dans Une Revue ChemSusChem Année : 2015

Thiazolylidene-Catalysed Cleavage of Methyl Oleate-Derived α-Hydroxyketone to the Corresponding Free Aldehydes

Résumé

Thiazolylidene-catalysed cleavage of the α-hydroxyketone derived from methyl oleate gave the corresponding aldehydes under non-oxidative conditions through a retro-benzoin process. The aldehydes produced are in equilibrium with their corresponding acyloins. To illustrate the synthetic utility of this protocol, the aldehydes were recovered by distillation.
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hal-03247545 , version 1 (03-06-2021)

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Elsa Deruer, Nicolas Duguet, Marc Lemaire. Thiazolylidene-Catalysed Cleavage of Methyl Oleate-Derived α-Hydroxyketone to the Corresponding Free Aldehydes. ChemSusChem, 2015, 8 (15), pp.2481-2486. ⟨10.1002/cssc.201500462⟩. ⟨hal-03247545⟩
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