V-Shaped Methylpyrimidinium Chromophores for Nonlinear Optics
Résumé
A series of four V-shaped methylpyrimidinium salts bearing diphenylamino-electron-donating groups appended at various pyrimidine positions were designed. These chromophores were obtained by regioselective N(1) monomethylation by methyl methanesulfonate of the pyrimidine core. Linear optical properties were studied experimentally and electronic properties were further completed by (TD)-DFT calculations. The second-order nonlinear optical (NLO) properties were also studied using electric field induced second harmonic generation (EFISH) method in chloroform, and all pyrimidinium salts exhibited μβ(0) >1000×10(-48) esu. The 2,4-disubstituted pyrimidinium core is preferred over 4,6-disubstitution as it enhances the NLO response and increases the dipole moment. (E,E)-2,4-Bis[4-(diphenylamino)styryl]-1-methylpyrimidin-1-ium methanesulfonate appears to be the best NLO-phore in chloroform in the series (μβ(0) =2500×10(-48) esu) and a figure of merit μβ(0) /MW=3.4 10(-48) esu mol g(-1) .
Domaines
Chimie
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Achelle et al. - 2021 - V‐Shaped Methylpyrimidinium Chromophores for Nonli.pdf (1.06 Mo)
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achelle_cplu202100081-sup-0001-misc_information.pdf (1.34 Mo)
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