As a part of an effort to determine the energy balance at the pool fire surface in compartments, a series of fire experiments were conducted to study heat flux of the flame in a vitiated environment formed with air and combustion products gases. This paper presents experimental results of the burning behaviour of a heptane pool fire in a reduced scale compartment equipped with a mechanical ventilation network. Measurements of heat fluxes, fuel mass loss rate, oxygen concentration and temperature are performed for heptane fires of 0.26 and 0.3 m diameter pans at different ventilation flow rates. An original method to separate effects of the radiant heat flux of the flame and of the external heat feedback to the fuel surface is developed. This was achieved by using an additional heat flux measurement located under the pool fire. A correlation was also developed to determine the temperature rise on the plume centerline in the compartment as a function of the heat release rate. The results indicate a decrease in the fuel mass loss rate, flame temperature and heat fluxes to the fuel surface as the oxygen concentration measured near the fuel decreases by varying the air refresh rate of the compartment. The flame radiation fraction shows a similar behaviour, whereas the convective fraction of the flame heat flux increases when oxygen concentration decreases. Based on these experimental findings, it was discussed that any classification of the burning regime of a pool fire should consider both the effects of pan diameter and the burning response to vitiated air. © 2013 Elsevier Ltd. All rights reserved.