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Article Dans Une Revue Chemical Record Année : 2021

Effective Tools for the Metal-catalyzed Regiodivergent Direct Arylations of (Hetero)arenes

Résumé

The direct functionalization of two different C-H bonds of the same organic molecule using different procedures - also called regiodivergent C-H bond functionalization - currently represents an important research topic in organic chemistry, as it demonstrates the versatility of C-H bond functionalization methodology. Over the last decade, the number of tools to control such regiodivergent C-H bond functionalizations has increased significantly. In this account, we will present the various tools that allowed us to arylate different positions of various (hetero)arenes, via a C-H bond functionalization, using palladium or ruthenium catalysis.
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Dates et versions

hal-03100367 , version 1 (16-02-2021)

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Hai-Yun Huang, Amal Benzai, Xinzhe Shi, Henri Doucet. Effective Tools for the Metal-catalyzed Regiodivergent Direct Arylations of (Hetero)arenes. Chemical Record, 2021, 21 (2), pp.343-356. ⟨10.1002/tcr.202000145⟩. ⟨hal-03100367⟩
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