A new “bicycle helmet”-like copper( ii ),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2018

A new “bicycle helmet”-like copper( ii ),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity

Résumé

Sydnones are mesioionic compounds studied for years for their versatile reactivity in substitution reactions, sydnone-alkyne or sydnone-alkene cycloaddition reactions. This perspective article focuses on the use of sydnones in coordination complexes, either through a metalation on one of the carbons of the sydnone ring, its modification to obtain polydentate ligands, or its use as a polar moiety that could influence the properties of the final complex. Such compounds are valuable either from a synthetic point of view or for their biological properties.

Domaines

Chimie
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Dates et versions

hal-03094977 , version 1 (04-01-2021)

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Alena Kulakova, Alexey N. Bilyachenko, Alexander A. Korlyukov, Lidia S. Shul'Pina, Xavier Bantreil, et al.. A new “bicycle helmet”-like copper( ii ),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity. Dalton Transactions, 2018, 47 (44), pp.15666-15669. ⟨10.1039/c8dt03209b⟩. ⟨hal-03094977⟩
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