Synthesis of a Multichromophoric Array by Sequential CuAAC Reactions
Résumé
An easily synthesized α-hydroxy-β-azidotetrazole scaffold was used to build a three dimensional polychromic system. Different chromophores (coumarin, BODIPY and distyryl BODIPY) were incorporated into the structure by using sequential CuAAC reactions to form a series of dyads and a triad. A computational study of the resulting arrays showed that the predominant conformations brought the substituents into close spatial proximity. The triad exhibited FRET behaviour with notably efficient energy transfer values.
Domaines
Chimie
Fichier principal
dyes and pigments Tafrioucht 2020.pdf (1.56 Mo)
Télécharger le fichier
Supporting Information-revised form.pdf (3.53 Mo)
Télécharger le fichier
Origine | Fichiers produits par l'(les) auteur(s) |
---|