Molecular catalysis of CO 2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Society Reviews Année : 2020

Molecular catalysis of CO 2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes

E. Boutin
  • Fonction : Auteur
L. Merakeb
  • Fonction : Auteur
B. Ma
  • Fonction : Auteur
B. Boudy
  • Fonction : Auteur
M. Wang
  • Fonction : Auteur
J. Bonin
  • Fonction : Auteur
M. Robert
  • Fonction : Auteur

Résumé

Earth-abundant Fe, Ni, and Co aza macrocyclic and polypyridine complexes have been thoroughly investigated for CO 2 electrochemical and visible-light-driven reduction. Since the first reports in the 1970s, an enormous body of work has been accumulated regarding the two-electron two-proton reduction of the gas, along with mechanistic and spectroscopic efforts to rationalize the reactivity and establish guidelines for structure-reactivity relationships. The ability to fine tune the ligand structure and the almost unlimited possibilities of designing new complexes have led to highly selective and efficient catalysts. Recent efforts toward developing hybrid systems upon combining molecular catalysts with conductive or semi-conductive materials have converged to high catalytic performances in water solutions, to the inclusion of these catalysts into CO 2 electrolyzers and photo-electrochemical devices, and to the discovery of catalytic pathways beyond two electrons. Combined with the continuous mechanistic efforts and new developments for in situ and in operando spectroscopic studies, molecular catalysis of CO 2 reduction remains a highly creative approach.
Fichier principal
Vignette du fichier
Boutin-et-al-ChemSocRev_2020.pdf (10.58 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03013208 , version 1 (18-11-2020)

Identifiants

Citer

E. Boutin, L. Merakeb, B. Ma, B. Boudy, M. Wang, et al.. Molecular catalysis of CO 2 reduction: recent advances and perspectives in electrochemical and light-driven processes with selected Fe, Ni and Co aza macrocyclic and polypyridine complexes. Chemical Society Reviews, 2020, 49 (16), pp.5772-5809. ⟨10.1039/D0CS00218F⟩. ⟨hal-03013208⟩
14 Consultations
70 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More