Unexpected disruption of the dimensionality-driven two-photon absorption enhancement within a multipolar polypyridyl ruthenium complex series
Résumé
The dimensionality-driven two-photon absorption (2PA) enhancement effect is investigated in a series of functionalized bipyridyl Ru-complexes. Our design strategy leads to very high 2PA responses up to ∼1500 GM. However, we highlight that the 2PA performance vs. dimensionality correlation reaches an unexpected limit stemming from 'anti-cooperative' interchromophoric couplings.
Domaines
Chimie
Fichier principal
Durand et al-2020-Unexpected Disruption of the Dimensionality-driven Two-Photon.pdf (1.11 Mo)
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Durand-ESI_RuL_Chem_Comm_Rev-3.pdf (1.91 Mo)
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| Origine | Fichiers produits par l'(les) auteur(s) |
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