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Article Dans Une Revue Chemical Communications Année : 2020

Isolated zirconium centres captured from aqueous solution: the structure of zirconium mandelate revealed from NMR crystallography

Résumé

Zirconium tetramandelate (2-hydroxy-2-phenylacetate) has been used for selective gravimetric analysis of zirconium for over 70 years. Herein its crystal structure is reported from synchrotron powder X-ray diffraction and 13 C solid-state NMR. The complex is a rare example of isolated zirconium cations, rather than the clusters prevalent in aqueous solutions.
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hal-02957644 , version 1 (30-11-2020)

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James Crosland, Emily Corlett, Dave Scapens, Nathalie Guillou, Steven Brown, et al.. Isolated zirconium centres captured from aqueous solution: the structure of zirconium mandelate revealed from NMR crystallography. Chemical Communications, 2020, 56 (70), pp.10159-10162. ⟨10.1039/d0cc03647a⟩. ⟨hal-02957644⟩
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