Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium( ii ) and its deuterated analog by luminescence spectroscopy at variable pressure - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2016

Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium( ii ) and its deuterated analog by luminescence spectroscopy at variable pressure

Elodie Tailleur
Christian Reber
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Résumé

We present the variable–pressure d–d luminescence spectra of crystalline bis-dimethyldithiocarbamate palladium(II) and its deuterated analog. The energies and shifts of the band maxima provide evidence for intermolecular Pd⋯H–C interactions, with quantitative differences observed for the deuterated complex. Shifts show distinct interactions in three pressure ranges between 1 bar and 85 kbar.
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hal-02955796 , version 1 (20-01-2022)

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Stéphanie Poirier, Elodie Tailleur, Hudson Lynn, Christian Reber. Characterization of Pd⋯H–C interactions in bis-dimethyldithiocarbamate palladium( ii ) and its deuterated analog by luminescence spectroscopy at variable pressure. Dalton Transactions, 2016, 45 (27), pp.10883-10886. ⟨10.1039/c6dt01574c⟩. ⟨hal-02955796⟩
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