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Article Dans Une Revue ChemCatChem Année : 2020

Transformations of bio-sourced 4-hydroxyphenylpropanoids based on olefin metathesis

Résumé

4-Hydroxyphenylpropanoids represent an important class of natural products directly extracted from plants or derived from lignocelullosic materials. They are phenol derivatives equipped with a terminal propenyl group, which is perfectly suited for applications involving olefin metathesis processes. In this review, we show that conditions have been found to achieve their self-metathesis, cross metathesis as well as some sequential transformations with metathesis as a key step with high yields and controlled stereoselectivities. Some applications in multi-step synthesis of biological relevant natural products involving metathetic transformations of 4-hydroxyphenylpropanoids are also reported.
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Dates et versions

hal-02936696 , version 1 (15-09-2020)

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H. Bilel, N. Hamdi, Cédric Fischmeister, Christian Bruneau. Transformations of bio-sourced 4-hydroxyphenylpropanoids based on olefin metathesis. ChemCatChem, 2020, 12 (20), pp.5000-5021. ⟨10.1002/cctc.202000959⟩. ⟨hal-02936696⟩
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