Journal Articles Polymer Year : 2002

Synthesis and blue luminescence of a soluble newly designed carbazole main-chain polymer

C. Olivero
  • Function : Author
D. Adès
  • Function : Author
M.-C. Castex
  • Function : Author
A. Siove
  • Function : Author

Abstract

A new electroactive polymer with alternating conjugated–nonconjugated repeating units in the main chain was synthesized by step growth polymerization of α,ω-bis(N-carbazolyl)octane in chloroform solution with excess of iron trichloride, and in the presence of N-ethylcarbazole as a terminating agent. The resulting α,ω-N-ethylcarbazole terminated poly(3,3′-bicarbazyl-N,N′-octylene)s are readily soluble in common organic solvents and have good film-forming capabilities, partly because of the special design of the polymer backbone constituted by stiff bicarbazyl chromophores linked by flexible eight-carbon segments. Soluble materials with molecular weights up to 105 g/mol and polydispersity indices around 3.3 were obtained. Purified samples exhibiting quite low polydispersity indices (in the range 1.5–1.7) can be prepared by a selective fractionation of the crude polymer from benzene/methanol mixtures. Structural analysis of these new ‘stairs-like’ polymers disclosed their well-defined character with an aromatic linkage exclusively at position 3 on the carbazole moieties. Electrochemical studies of polymer films exhibited two reversible redox processes between 0 and 1.5 V vs saturated calomel electrode. The photoluminescence (PL) of the polymer in solution and as cast films revealed an intense blue emission and the same intensity level than that of the N,N′-diethyl-3,3′-bicarbazyl molecule, taken as a model of the aromatic segment of the repeating unit. Such a processable and purifiable polymer with bicarbazyl-isolated fluorophores is quite promising for the fabrication of efficient blue light-emitting devices.

Domains

Polymers

Dates and versions

hal-02930287 , version 1 (04-09-2020)

Identifiers

Cite

E. Cloutet, C. Olivero, D. Adès, M.-C. Castex, A. Siove. Synthesis and blue luminescence of a soluble newly designed carbazole main-chain polymer. Polymer, 2002, 43 (12), pp.3489-3495. ⟨10.1016/S0032-3861(02)00080-0⟩. ⟨hal-02930287⟩

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