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Article Dans Une Revue Dalton Transactions Année : 2013

On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study

Résumé

The prevalence of a counterintuitive carbene conformation in a series of piano-stool Mn(I) alkylalkoxycarbene complexes was rationalized by means of DFT calculations and high-resolution XRD analysis in terms of stabilizing non-covalent C–H⋯C[triple bond, length as m-dash]O interligand interactions.
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hal-02908209 , version 1 (28-07-2020)

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Noël Lugan, Israel Fernández, Rémy Brousses, Dmitry A. Valyaev, Guy Lavigne, et al.. On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study. Dalton Transactions, 2013, 42 (4), pp.898-901. ⟨10.1039/C2DT32554C⟩. ⟨hal-02908209⟩
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