Synthesis and Photophysical Properties of Copper(I) Complexes Obtained from 1,10-Phenanthroline Ligands with Increasingly Bulky 2,9-Substituents - Archive ouverte HAL Access content directly
Journal Articles European Journal of Inorganic Chemistry Year : 2010

Synthesis and Photophysical Properties of Copper(I) Complexes Obtained from 1,10-Phenanthroline Ligands with Increasingly Bulky 2,9-Substituents

Abstract

In this paper, we describe the synthesis and the electronic properties of a series of [Cu(NN)(2)](+) systems. The NN ligands investigated are 2,9-bis[(tert-butyldimethylsilyloxy)methyl]-1,10-phenanthroline (1), 2,9-bis[(triisopropylsilyloxy)methyl]-1,10-phenanthroline (2), 2,9-bis[(tert-butyldiphenylsilylmoxy) ethyl]-1, 10 -phenanthroline(3), 2,9-bis[2,6-bis(benzyloxy)phenethyl]-1,10-phenanthroline (4) and 2-(1,3-diphenylpropan-2-yl)-9-phenethyl-1,10-phenanthroline (5). The electrochemical properties and the ground state electronic.

Dates and versions

hal-02908203 , version 1 (28-07-2020)

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Gianluca Accorsi, Nicola Armaroli, Carine Guyard-Duhayon, Alix Sournia-Saquet, Béatrice Delavaux-Nicot, et al.. Synthesis and Photophysical Properties of Copper(I) Complexes Obtained from 1,10-Phenanthroline Ligands with Increasingly Bulky 2,9-Substituents. European Journal of Inorganic Chemistry, 2010, 2010 (1), pp.164-173. ⟨10.1002/ejic.200900954⟩. ⟨hal-02908203⟩
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