Long Lived Charge Separation in Iridium(III)-Photosensitized Polyoxometalates: Synthesis, Photophysical and Computational Studies of Organometallic\textendashRedox Tunable Oxide Assemblies - Archive ouverte HAL
Article Dans Une Revue Chemical Science Année : 2013

Long Lived Charge Separation in Iridium(III)-Photosensitized Polyoxometalates: Synthesis, Photophysical and Computational Studies of Organometallic\textendashRedox Tunable Oxide Assemblies

Résumé

Keggin and Dawson-type polyoxometalates (POMs) covalently grafted to heteroleptic cyclometalated iridium(iii) complexes (POM\textendash[Ir] dyads) have been prepared by postfunctionalization of organosilyl and organotin POM derivatives. Electronic properties of these 4 photosensitized POM\textendash[Ir] dyads were evaluated by

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https://hal.science/hal-02878864

Soumis le : mardi 23 juin 2020-12:39:41

Dernière modification le : jeudi 28 novembre 2024-10:50:34

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hal-02878864 , version 1 (23-06-2020)

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Benjamin Matt, Xu Xiang, Alexey L. Kaledin, Nannan Han, Jamal Moussa, et al.. Long Lived Charge Separation in Iridium(III)-Photosensitized Polyoxometalates: Synthesis, Photophysical and Computational Studies of Organometallic\textendashRedox Tunable Oxide Assemblies. Chemical Science, 2013, 4 (4), pp.1737--1745. ⟨10.1039/C3SC21998D⟩. ⟨hal-02878864⟩

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