Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice? - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Catalysis Communications Année : 2020

Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice?

Résumé

Self-assembled tetranuclear molybdenum(vi) complexes with hydrazonato ligands, [MoO2L]4, were tested as (pre)catalysts for cyclooctene and cyclohexene epoxidation without extra organic solvent added. Special attention was addressed to the comparison of oxidizing agents, TBHP in water vs. TBHP in decane. The idea was to test the greenness of the complete process. Density Functional Theory calculations were used to support and explain experimental catalytic result for tetranuclear self-assembled systems.

Dates et versions

hal-02877604 , version 1 (22-06-2020)

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Citer

Jana Pisk, Dominique Agustin, Višnja Vrdoljak. Tetranuclear molybdenum(vi) hydrazonato epoxidation (pre)catalysts: Is water always the best choice?. Catalysis Communications, 2020, 142, pp.106027. ⟨10.1016/j.catcom.2020.106027⟩. ⟨hal-02877604⟩
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