A multi-stream Flamelet Progress Variable (FPV) model, specifically developed for coal combustion, is proposed. The model accounts for the different fuel streams associated with the volatile and char burnout products. The applicability of the new FPV model is investigated in a laminar stagnation pulverized coal flame. The flame considered is a premixed mixture of CH 4 , O 2 and N 2 , carrying pulverized coal particles, stabilized in an impinging wall. Spontaneous emissions of OH * , CH * and C * 2 are measured to identify the flame. The 1D numerical simulations of the experimental conditions are able to reproduce the main features of the flame. The applicability of the multi-stream FPV model to coal combustion is further evaluated with the a posteriori analysis of the FPV results, comparing the results with a reference model, where the species are fully transported and the chemistry directly evaluated. Then, with the budget analysis, the influence of the control variables used to build the look-up table is assessed by examining the conditional contributions to the overall transport terms of scalar quantities (e.g. species, temperature). The results of both analyses show that the proposed multi-stream FPV model can accurately predict the main features of coal combustion, with only minor issues related to the manifold used to build the look-up table.