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Journal Articles Chemical Communications Year : 2019

A single-crystal-to-single-crystal transformation affording photochromic

Abstract

Metal-organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described. These metal-organic rotaxane frameworks (MORF) are obtained by desolvation of a crystal precursor featuring a network already near-optimal toward 3D metal-ligand reticulation and show reversible photochromism.
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Dates and versions

hal-02491566 , version 1 (07-12-2020)

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Xue Yang, Michel Giorgi, Hakim Karoui, Didier Gigmes, Virginie Hornebecq, et al.. A single-crystal-to-single-crystal transformation affording photochromic. Chemical Communications, 2019, 55 (92), pp.13824--13827. ⟨10.1039/c9cc07121k⟩. ⟨hal-02491566⟩
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