Reactions of antioxidants with molecular oxygen. Part II. Isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate in silicone matrix - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Polymer Degradation and Stability Année : 2011

Reactions of antioxidants with molecular oxygen. Part II. Isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate in silicone matrix

Résumé

The study of oxidation kinetics of isooctyl-3-(3,5-di-tert-butyl-4- hydroxyphenyl)propionate (Irganox 1135) stabiliser was carried out using silicone oil as an inert substrate. The stabiliser was exposed at 80-120 °C under 0.02-3.0 MPa oxygen pressure. UV/VIS spectrophotometry, gel permeation chromatography and high pressure liquid chromatography were used to follow the stabiliser consumption, whose kinetic parameters were determined by applying a simple kinetic model.
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hal-02456020 , version 1 (27-01-2020)

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Rosa Navarro, Ludmila Audouin, Jacques Verdu. Reactions of antioxidants with molecular oxygen. Part II. Isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate in silicone matrix. Polymer Degradation and Stability, 2011, 96 (5), pp.965-973. ⟨10.1016/j.polymdegradstab.2011.01.024⟩. ⟨hal-02456020⟩
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