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Article Dans Une Revue Cellulose Chemistry and Technology Année : 2019

VISCOSITY OF HYDROXYPROPYL CELLULOSE SOLUTIONS IN NON-ENTANGLED AND ENTANGLED STATES

Résumé

The viscosity of isotropic hydroxypropyl cellulose (HPC) solutions was investigated in pure water and aqueous solution of 10% glucose as solvent. The intrinsic viscosity, [], was determined by using an approach developed by Wolf which is able to describe the viscosity evolution over a large domain of concentrations (c) for any type of macromolecular structure. The transition between dilute solution (i.e., the state with isolated non-interacting coils) and semidilute solution (i.e., a state where coils are touching each other but with not so many interactions between chains) was evidenced for HPC solutions. The flow curves were determined in semidilute concentration regime and give access to the Newtonian viscosity. From the plot of the specific viscosity as a function of a dimensionless parameter, c[] (defined as reduced concentration), the entangled and non-entangled states were delimitated for HPC aqueous solutions. A critical overlap parameter of 2.4 was determined. In aqueous solution of 10% glucose the semidilute non-entangled state was depicted for high molecular HPC in the investigated range of concentrations (bellow 4 g/dL).

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Matériaux
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Dates et versions

hal-02439814 , version 1 (14-01-2020)

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  • HAL Id : hal-02439814 , version 1

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Maria Bercea, Patrick Navard. VISCOSITY OF HYDROXYPROPYL CELLULOSE SOLUTIONS IN NON-ENTANGLED AND ENTANGLED STATES. Cellulose Chemistry and Technology, 2019. ⟨hal-02439814⟩
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