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Article Dans Une Revue New Journal of Chemistry Année : 2018

Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization

Résumé

Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.

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Dates et versions

hal-02381291 , version 1 (26-11-2019)

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  • HAL Id : hal-02381291 , version 1

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Xiaoqin Jiang, Wengian Shan, Nicolas Desbois, Valentin Quesneau, Stéphane Brandès, et al.. Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization. New Journal of Chemistry, 2018, 42 (10), pp.8220 - 8229. ⟨hal-02381291⟩
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