The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H- pyrrolo[1,2-c]imidazolo[5,4-b]indole
Résumé
This paper is dedicated to Henk van der Plas who has for many years inspired heterocyclic chemists the world over with his innovative research, his impeccable standards and his charming personality Abstract N-3-(1-Methylindol-3-yl)propan-N-(2,2,2-trichloroethoxysulfonyl)guanidine was synthesized from 3-formyl-1-methylindole in six steps and subjected to conditions intended to convert the side-chain into a 2-iminotetrahydropyrimidine-containing product, of relevance to a possible synthesis of the aplicyanins. An alternative reaction course was observed, resulting in the formation of a new tetracyclic system.
Domaines
ChimieOrigine | Fichiers éditeurs autorisés sur une archive ouverte |
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