The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H- pyrrolo[1,2-c]imidazolo[5,4-b]indole - Archive ouverte HAL
Article Dans Une Revue ARKIVOC - Online Journal of Organic Chemistry Année : 2009

The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H- pyrrolo[1,2-c]imidazolo[5,4-b]indole

Keith Mills
  • Fonction : Auteur
John A Joule
  • Fonction : Auteur

Résumé

This paper is dedicated to Henk van der Plas who has for many years inspired heterocyclic chemists the world over with his innovative research, his impeccable standards and his charming personality Abstract N-3-(1-Methylindol-3-yl)propan-N-(2,2,2-trichloroethoxysulfonyl)guanidine was synthesized from 3-formyl-1-methylindole in six steps and subjected to conditions intended to convert the side-chain into a 2-iminotetrahydropyrimidine-containing product, of relevance to a possible synthesis of the aplicyanins. An alternative reaction course was observed, resulting in the formation of a new tetracyclic system.

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Chimie
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Dates et versions

hal-02364302 , version 1 (14-11-2019)

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Daniel Pla, Keith Mills, John A Joule, Fernando Albericio, Mercedes Alvarez. The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H- pyrrolo[1,2-c]imidazolo[5,4-b]indole. ARKIVOC - Online Journal of Organic Chemistry, 2009, ⟨10.3998/ark.5550190.0010.626⟩. ⟨hal-02364302⟩
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