Correction to: A Single-Molecule Magnet Tetranuclear [Mn 3 III MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Cluster Science Année : 2019

Correction to: A Single-Molecule Magnet Tetranuclear [Mn 3 III MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands

Résumé

Treatment of Mn(OAc)2.4H2O with 3 equiv. HN(iPr2PO)2 in the presence of nBu4NCl in acetonitrile resulted in isolation of a tetranuclear {Mn3IIIMnIV} complex [Mn4(l3-O)3(l3-Cl)(l-OAc)3{N(iPr2PO)2}3].0.5C6H14 (1.0.5C6H14), and a dinuclear {MnIIMnIII} complex [Mn2{N(iPr2PO)2}{l2,g3-(iPrPO2)NH(iPr2PO)}2{g2-(iPrPO2)NH(iPr2PO)}2].0.25AcOH (2.0.25AcOH) with bis(diisopropylphosphinyl)imide ligands. The solid-state structures of two complexes have been established by single-crystal X-ray crystallography. The tetranuclear complex 1 belongs to a family of {Mn3 IIIMnIVO3X} single-molecule magnets (SMMs) with effective energy barrier of 14.3 K by some further magnetic characterizations.
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hal-02349118 , version 1 (23-11-2020)

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Wai-Man Cheung, Qian-Feng Zhang, Rodolphe Clérac, Ian Hewitt, Christopher Anson, et al.. Correction to: A Single-Molecule Magnet Tetranuclear [Mn 3 III MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands. Journal of Cluster Science, 2019, ⟨10.1007/s10876-019-01693-7⟩. ⟨hal-02349118⟩

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