Correction to: A Single-Molecule Magnet Tetranuclear [Mn 3 III MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands
Résumé
Treatment of Mn(OAc)2.4H2O with 3 equiv. HN(iPr2PO)2 in the presence of nBu4NCl in acetonitrile resulted in isolation of
a tetranuclear {Mn3IIIMnIV} complex [Mn4(l3-O)3(l3-Cl)(l-OAc)3{N(iPr2PO)2}3].0.5C6H14 (1.0.5C6H14), and a dinuclear
{MnIIMnIII} complex [Mn2{N(iPr2PO)2}{l2,g3-(iPrPO2)NH(iPr2PO)}2{g2-(iPrPO2)NH(iPr2PO)}2].0.25AcOH
(2.0.25AcOH) with bis(diisopropylphosphinyl)imide ligands. The solid-state structures of two complexes have been
established by single-crystal X-ray crystallography. The tetranuclear complex 1 belongs to a family of {Mn3
IIIMnIVO3X} single-molecule magnets (SMMs) with effective energy barrier of 14.3 K by some further magnetic characterizations.
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