Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu 2 (OH) 3 (C 12 H 25 SO 4 )

Single-crystals of the layered copper hydroxide dodecylsulfate Cu2(OH)3(C12H25SO4) have been obtained for the first time, by controlled hydrolysis of an aqueous copper acetate solution. Interestingly this compound crystallizes in a non-centrosymmetric space group (P21, a = 5.591(10) Å, b = 6.108(11) Å, c = 26.96(5) Å,  =  = 90°,  = 92.76°), which is further confirmed by non-linear optical measurements. Within the course of the synthesis, a probable intermediate

Mots clés

Non-linear optics non-centrosymmetric Morphology Copper Layered Simple Hydroxide Dodecylsulfate Space group Molecules Anions Crystal structure

Domaines

Chimie Cristallographie Chimie de coordination Chimie inorganique

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Revised manuscript without highlights.pdf (2.17 Mo)

Origine	Fichiers produits par l'(les) auteur(s)

Guillaume Rogez : Connectez-vous pour contacter le contributeur

https://hal.science/hal-02324938

Soumis le : mardi 22 octobre 2019-10:18:23

Dernière modification le : mercredi 4 septembre 2024-03:05:12

Archivage à long terme le : jeudi 23 janvier 2020-15:00:51

Dates et versions

hal-02324938 , version 1 (22-10-2019)

Identifiants

HAL Id : hal-02324938 , version 1
DOI : 10.1021/acs.cgd.7b01692

Citer

Quentin Evrard, Cédric Leuvrey, Pierre Farger, Émilie Delahaye, Pierre Rabu, et al.. Noncentrosymmetric Cu(II) Layered Hydroxide: Synthesis, Crystal Structure, Nonlinear Optical, and Magnetic Properties of Cu 2 (OH) 3 (C 12 H 25 SO 4 ). Crystal Growth & Design, 2018, 18 (3), pp.1809-1817. ⟨10.1021/acs.cgd.7b01692⟩. ⟨hal-02324938⟩

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