The question of material stability through the determination of the thermodynamic properties is of fundamental and technological importance to any analysis of system properties in many applications. For Al 4 C 3 , its experimental heat of formation varies widely, from −0.187 to −0.363 eV/atom, which makes it difficult to use such experimental information for any reactivity assessment. Here, we demonstrate that density functional theory (DFT), with the recently developed strongly constrained and appropriately normed (SCAN) functional, is especially powerful in critically assessing these experimental data. In order to have a more complete description of thermodynamic properties of Al 4 C 3 , we also determine the temperature dependence of its heat capacity using both the harmonic and quasi-harmonic approximation. In addition, and to select the most efficient approximation , we come back to the experimental background by using differential scanning calorimetry (DSC) to measure this quantity at constant pressure up to high temperatures, namely 873 K.