Article Dans Une Revue Coordination Chemistry Reviews Année : 2017

Coordination Polymers based on calixarene derivatives: Structures and properties

Résumé

The solid-state structures of 1D-3D Coordination Polymers based on the macrocyclic calixarene backbone has been reviewed, based on the chemical nature of appended substituents of macrocycle platform. The coordination propensity of this class of ligands is analysed, taking into account the different coordinating atoms/groups that can be located on the macrocyclic ligand: (1) the unmodified inherently coordinating thiacalix[4]arene with the S bridge a donor atoms; (2) different conformations of calix[n]arene units, with appended O donor atoms; (3) the chemical modification of the upper rim of calix[n]arenes and thiacalix[n]arenes, with coordinating groups, in particular the use of the sulfonate groups and (4) calix[4]arenes, thiacalix[4]arenes and tetramercaptothiacalix[4]rene that have been modified at their lower rim (mono, di and tetra substitution) using coordinating groups like cyano, carboxylate, pyridyl and pyrazolyl groups. All the formed coordination networks have been described. A special attention has been drawn to the structural and functional properties of these extended networks: magnetic, luminescence, adsorption and catalytic properties. Perspectives and future challenges in this emerging field are also discussed.

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hal-02300943 , version 1 (25-11-2020)

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Alexander Ovsyannikov, Svetlana Solovieva, Igor Antipin, Sylvie Ferlay. Coordination Polymers based on calixarene derivatives: Structures and properties. Coordination Chemistry Reviews, 2017, 352, pp.151-186. ⟨10.1016/j.ccr.2017.09.004⟩. ⟨hal-02300943⟩
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