Comparison of two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)]·H2O
Résumé
The two polymeric transition metal complexes with 1, 4-benzenedicarboxylate ions as bridging ligands were compared. The structures of the complexes were analyzed using low-temperature data collected at 193.2 K. The two complexes were in the form of zigzag chains. The Co ion was five coordinate with a distorted trigonal-bipyramidal geometry in the first compound. The Cu ion in the second complex was in a distorted octahedral 4+2 environment.