Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)
Résumé
α-Alkynyl-α′-trimethylsilylhydrazones are used as novel Rh(II)-carbenoids precursors. These new carbenoids have shown very good reactivity in Si−H insertion reactions, leading to original propargylic geminal-bis(silanes) in a two-step sequential process.
Domaines
Chimie organique| Origine | Fichiers produits par l'(les) auteur(s) |
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