Visible-Light-Triggered, Metal- and Photocatalyst-Free Acylation of N-Heterocycles - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2018

Visible-Light-Triggered, Metal- and Photocatalyst-Free Acylation of N-Heterocycles

Résumé

A photoinduced acylation of N-heterocycles is explored. This visible-light triggered reaction occurs not only under extremely mild reaction conditions, but also does not require the presence of a photosensitizer. The mechanistic studies suggest formation of EDA complexes prompt to harness the energy from visible-light. Compatibility with a large panel of α-keto acids as acyl precursors and an array of N-heterocycles clearly showcase the synthetic potential of this handy and green acylation protocol.

Mots clés

Domaines

Chimie organique
Fichier non déposé

Dates et versions

hal-02153060 , version 1 (11-06-2019)

Identifiants

Citer

Lucas Guillemard, Francoise Colobert-Leuenberger, Joanna Wencel-Delord. Visible-Light-Triggered, Metal- and Photocatalyst-Free Acylation of N-Heterocycles. Advanced Synthesis and Catalysis, 2018, 360 (21), pp.4184-4190. ⟨10.1002/adsc.201800692⟩. ⟨hal-02153060⟩
56 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More