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Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2014

Transition Metal-Mediated Direct C-H Arylation of Heteroarenes Involving Aryl Radicals

Résumé

This review gives an overview of the generation of aryl radicals, mediated by transition metals, and their use for the CH arylation of heteroarenes. The different sources of aromatic derivatives able to generate aryl radicals via a metal-assisted reduction or oxidation are discussed, with a critical view of the developed systems. The radical arylations of nitrogen-, oxygen- or sulfur-containing heterocycles are then described and mechanistic considerations are discussed as well.

Domaines

Chimie

Dates et versions

hal-02142277 , version 1 (28-05-2019)

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Citer

Helene Bonin, Mathieu Sauthier, Francois-Xavier Felpin. Transition Metal-Mediated Direct C-H Arylation of Heteroarenes Involving Aryl Radicals. Advanced Synthesis and Catalysis, 2014, 356 (4), pp.645-671. ⟨10.1002/adsc.201300865⟩. ⟨hal-02142277⟩
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