Bifunctional magnetic luminescent particles based on iron oxide nanoparticles grafted with a europium silylated bypiridine tris(β-diketonate) complex - Archive ouverte HAL Access content directly
Journal Articles ChemistrySelect Year : 2016

Bifunctional magnetic luminescent particles based on iron oxide nanoparticles grafted with a europium silylated bypiridine tris(β-diketonate) complex

Abstract

A new highly magnetic-luminescent nanocomposites has been synthesized by grafting luminescent europium complex comprising tris(b-diketone) and bypridine ligand modified with a silylil function group (Eu[(TTA)3(Bpy-Si)] complex) on the surface of superparamagnetic iron oxide nanoparticles with 11 nm in size coated with a thin silica outer layer. The g-Fe2O3/SiO2 nanoparticles were fully characterized by ATR-FTIR, FE-SEM, HRTEM and magnetic measurements to confirm the structure of nanocomposite and the superparamagnetic behavior. Grafting with europium silylated bypiridine tris(b-diketonate) complex on nanoparticles surface was achieved by covalent bonding through triethoxysilyl groups which allows high concentration of the luminescent species. The resulting nanocomposite display superparamagnetic profile and the indirect excitation in the ultraviolet region outcomes high red luminescence intensity(at 613 nm) with narrow characteristic emission lines of Eu(III) and emission lifetime in the millisecond range. The nanocomposite is potentially useful for applications as biolabelling,imaging, bio-separation and bioassays.

Domains

Materials
Fichier principal
Vignette du fichier
Silva_16641.pdf (903.27 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

hal-02135663 , version 1 (21-05-2019)

Identifiers

Cite

Robson R. Silva, Adriana P. Duarte, Rafael M. Sábio, José M. A. Caiut, Marie Gressier, et al.. Bifunctional magnetic luminescent particles based on iron oxide nanoparticles grafted with a europium silylated bypiridine tris(β-diketonate) complex. ChemistrySelect, 2016, 1 (18), pp.5923-5928. ⟨10.1002/slct.201601203⟩. ⟨hal-02135663⟩
39 View
65 Download

Altmetric

Share

Gmail Facebook X LinkedIn More