A BN anthracene mimics the electronic structure of more highly conjugated systems - Archive ouverte HAL
Article Dans Une Revue Dalton Transactions Année : 2019

A BN anthracene mimics the electronic structure of more highly conjugated systems

Résumé

9a,9-BN anthracene was synthesized using a simple three-step sequence involving intramolecular electrophilic borylation of 2-benzylpyridines. The same procedure can be applied to yield a number of substituted 9a,9-BN anthracenes. Spectroscopic characterization of the parental compound (UV-photoelectron spectroscopy, UV-vis absorption/emission) shows an electronic structure more similar to that of a larger conjugated system rather than anthracene, the direct all-carbon analogue.
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Dates et versions

hal-02125180 , version 1 (10-05-2019)

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Jacob Ishibashi, Clovis Darrigan, Anna Chrostowska, Bo Li, Shih-Yuan Liu. A BN anthracene mimics the electronic structure of more highly conjugated systems. Dalton Transactions, 2019, 48 (8), pp.2807-2812. ⟨10.1039/c9dt00481e⟩. ⟨hal-02125180⟩
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