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Journal Articles European Journal of Inorganic Chemistry Year : 2008

Tetrahedral Assembly with Lanthanides: Toward Discrete Polynuclear Complexes

Gérald Bernardinelli
  • Function : Author
Yaroslav Filinchuk
  • Function : Author

Abstract

We report on the preparation of discrete 3D tetrametallic edifices containing trivalent lanthanides (Eu–Lu). Their formation is thermodynamically controlled through self‐assembly with a new tripodal ligand L possessing short binding strands. X‐ray crystallography shows that four nine‐coordinate cations adopt a regular tetrahedral arrangement in the solid state. These remarkable, highly charged structures are maintained in solution, as demonstrated by NMR spectroscopy, ESI‐MS and spectrophotometry.

Dates and versions

hal-02122713 , version 1 (07-05-2019)

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Josef Hamacek, Gérald Bernardinelli, Yaroslav Filinchuk. Tetrahedral Assembly with Lanthanides: Toward Discrete Polynuclear Complexes. European Journal of Inorganic Chemistry, 2008, 22, pp.3419-3422. ⟨10.1002/ejic.200800455⟩. ⟨hal-02122713⟩
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