Mixing processes of solid propellants can result in friction. Solid propellant ignitions can be observed under safety tests. Analysing a solid propellant elementary friction test from a mechanical, thermal, and physiochemical point of view, it appears that specific friction conditions allow the emergence of component flows in the solid propellant volume, readying the self-ignition. Numerical simulations of the solid propellant elementary friction test involve discrete elements to model these dynamic behaviours of the components within the contact. Indeed, comparisons between experiments and simulations are performed on mechanical parameters and on the evolution of the solid propellant components within the contact. Such comparisons exhibit qualitative and quantitative results by validating local parameters (adhesion), which make understand the solid propellant ignition scenario.