Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium - Archive ouverte HAL
Article Dans Une Revue Chemistry - A European Journal Année : 2015

Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium

Résumé

Herein, we report on the rational design, preparation and characterization of a novel homo-octanuclear helicate, which results from a spatial extension of the central tetranuclear platform. The 3D supramolecular assembly is obtained by complexing europium(III) with a new hexatopic tripodal ligand. The isolated octanuclear helicate is fully characterized by different methods clearly evidencing the structure predicted with molecular modelling. The ligand preorganization plays a crucial role in a successful self-assembly process and induces the formation of a well-defined triple-stranded helical structure. This prototypal octanuclear edifice accommodating functional lanthanides within a 3D scaffold offers attractive perspectives for further applications.

Dates et versions

hal-02072315 , version 1 (19-03-2019)

Identifiants

Citer

Soumaila Zebret, Eliane Vögele, Tomas Klumpler, Josef Hamacek. Designing Artificial 3D Helicates: Unprecedented Self-Assembly of Homo-octanuclear Tetrapods with Europium. Chemistry - A European Journal, 2015, 21 (18), pp.6695-6699. ⟨10.1002/chem.201500006⟩. ⟨hal-02072315⟩
21 Consultations
0 Téléchargements

Altmetric

Partager

More