Structural snapshots of the rearrangement of the bis(di- tert -butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2018

Structural snapshots of the rearrangement of the bis(di- tert -butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

Résumé

The bis(di-tert-butyl-aminophenyl)amine ligand H3LN,N,N was reacted with Mn(II), Co(II), Fe(III) and Cu(II) salts in air. The ligand undergoes oxidative transformations, which involve intra and intermolecular C–N and N–N bond formations. A rare aromatic C–N bond cleavage leading to a C–O bond has also been observed.

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Chimie
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Dates et versions

hal-02048054 , version 1 (25-02-2019)

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Citer

N. Leconte, B. Baptiste, C. Philouze, Fabrice Thomas. Structural snapshots of the rearrangement of the bis(di- tert -butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions. Dalton Transactions, 2018, 47 (33), pp.11303-11307. ⟨10.1039/c8dt02462f⟩. ⟨hal-02048054⟩
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