Single-Molecule Magnet Behavior in Dy 3+ Half-Sandwich Complexes Based on Ene-Diamido and Cp* Ligands
Résumé
We report in this communication the synthesis, structure and magnetic investigations of two new half-sandwich complexes [Dy(DAD)Cp*(THF)] (1) and [Li(THF) 3 ][Dy(DAD)Cp*Cl] (2) (Cp* = C 5 Me 5 , DAD = [2,6-iPr 2 C 6 H 3 N-CMeCMe-NC 6 H 3 iPr2-2,6). Both compounds exhibit zero-field SMM behavior but distinct relaxation dynamics originating from difference in the arrangement of Cp* and DAD ligands. The anisotropic barrier for 1 is found one order of magnitude greater than for 2.
Domaines
Chimie de coordination
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