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Chapitre D'ouvrage Année : 2017

Sulfur in Catalysis

Résumé

Sulfur has a deleterious reputation in catalysis and is considered to have a noxious effect on catalytic systems, because most of the time they become inactive. This chapter reviews the use of transition metal complexes in coordination catalysis when sulfur is present in a ligand as the atom coordinating to the metal center, or is just part of the ligand, organic synthesis is performed in which the catalyst is not affected by the presence of a sulfur atom on the substrate, a carbon-sulfur bond is obtained by catalysis, and artificial metalloenzymes are built containing, most of the time, especially designed ligands. In recent years, efficient catalytic systems have been found for the formation of carbon-sulfur bonds so that this strategy for preparing organic compounds for the pharmaceutical industry appears to be very attractive. Incorporation of catalytically efficient transition metal complexes within a host protein is a recent strategy for designing artificial metalloenzymes.
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Dates et versions

hal-02042488 , version 1 (20-02-2019)

Identifiants

  • HAL Id : hal-02042488 , version 1

Citer

Philippe Kalck. Sulfur in Catalysis. Cornils, B. and Herrmann, W. A. and Beller, M. and Paciello, R. Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook, 33, Wiley-VCH, pp.1557-1578, 2017, 978-3-52765-173-3. ⟨hal-02042488⟩
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