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Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2016

Cobalt-Catalyzed Reductive Cross-Coupling Between Benzyl Chlorides and Aryl Halides

Résumé

A new protocol for the direct reductive cobalt-catalyzed arylation of benzyl chlorides has been developed in order to form functionalized diarylmethanes. A variety of reactive groups either on the aryl or the benzyl halide was employed. This represents the first cobalt-catalyzed reductive cross-coupling which does not require any ligand and pyridine. A reaction pathway is proposed involving a radical benzyl species.
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hal-02000508 , version 1 (07-12-2023)

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Suman Pal, Sushobhan Chowdhury, Elodie Rozwadowski, Audrey Auffrant, Corinne Gosmini. Cobalt-Catalyzed Reductive Cross-Coupling Between Benzyl Chlorides and Aryl Halides. Advanced Synthesis and Catalysis, 2016, 358 (15), pp.2431-2435. ⟨10.1002/adsc.201600378⟩. ⟨hal-02000508⟩
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