Article Dans Une Revue Chemical Communications Année : 2014

A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene

Résumé

The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(l-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.

Dates et versions

hal-01996006 , version 1 (28-01-2019)

Identifiants

Citer

G. Deacon, Florian Jaroschik, P. Junk, Rory P Kelly. A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene. Chemical Communications, 2014, 50 (73), pp.10655-10657. ⟨10.1039/C4CC04427D⟩. ⟨hal-01996006⟩
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