Decarboxylative arylation of substituted pyrroles N-protected with 2-(trimethylsilyl)ethoxymethyl (SEM) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Canadian Journal of Chemistry Année : 2018

Decarboxylative arylation of substituted pyrroles N-protected with 2-(trimethylsilyl)ethoxymethyl (SEM)

Résumé

Palladium-catalyzed decarboxylative arylation is reported using pyrroles N-protected with the 2-(trimethylsilyl)ethoxymethyl (SEM) group and featuring 2-, 3-, and 4-substituents about the pyrrolic framework. In contrast to N-protected pyrroles previously used in decarboxylative arylation, the use of SEM allows deprotection under mild conditions.
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Dates et versions

hal-01950253 , version 1 (14-11-2021)

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Carlotta Figliola, Sarah Greening, Connor Lamont, Bandon R. Groves, Alison Thompson. Decarboxylative arylation of substituted pyrroles N-protected with 2-(trimethylsilyl)ethoxymethyl (SEM). Canadian Journal of Chemistry, 2018, ⟨10.1139/cjc-2017-0402⟩. ⟨hal-01950253⟩
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