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Article Dans Une Revue Chemical Communications Année : 2018

A supramolecular porous material comprising Fe(II) mesocates

Résumé

The dinuclear mesocate [Fe2L3](BF4)4, 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N2.

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Matériaux
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Dates et versions

hal-01945656 , version 1 (05-12-2018)

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  • HAL Id : hal-01945656 , version 1

Citer

Benjamin Wilson, Hayley Scott, Omid Qazvini, Shane Telfer, Corine Mathonière, et al.. A supramolecular porous material comprising Fe(II) mesocates. Chemical Communications, 2018, 54 (95), pp.13391-13394. ⟨hal-01945656⟩
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