Orientations and texture instabilities in graphene oxide liquid crystals
Résumé
Graphene oxide dispersions are easily obtained in water. Due to the high aspect ratio of the flakes, liquid crystals
then forms a nematic phase at moderate concentrations [1,2], which allows to design various composites with
nanoparticles. Preparing organized materials and thin films from these dispersions however requires a good controlof the liquid crystal ordering during the deposition and the drying of the films.
Here we have focused on mechanical instabilities that are frequently observed in thin graphene liquid crystal
layers, when they are submitted to weak constraints. We have shown how to create and stabilize large-sized
periodic textures (millimeter scale, see fig.1). The patterns have been characterized under optical and electronic
microscopies. They result from the peculiar elastic and rheological properties of the graphene oxide liquid crystals.
Our results also clarify why long-standing hypotheses on the presence of exotic phases [1] at large concentrations
are present in the literature.