Journal Articles Chemistry - A European Journal Year : 2018

Transition-Metal-Free Synthesis of Biarylmethanes from Aryl Iodides and Benzylic Ketones

Abstract

An original metal-free procedure for the synthesis of biarylmethanes is disclosed herein. The reactions occur with high selectivity starting from aryl iodides and benzylic ketones in the presence of superbasic media (CsOH/DMSO). This procedure allows a straightforward access to a wide range of biarylmethane derivatives substituted with electron-withdrawing and -donating substituents.

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hal-01925977 , version 1 (18-11-2018)

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Martin Pichette drapeau, Anis Tlili, Yassir Zaid, Dounia Toummini, Fouad Ouazzani chahdi, et al.. Transition-Metal-Free Synthesis of Biarylmethanes from Aryl Iodides and Benzylic Ketones. Chemistry - A European Journal, 2018, 24 (17449), ⟨10.1002/chem.201804415⟩. ⟨hal-01925977⟩
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