Substituent effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands
Résumé
Molybdenum complexes of type [MoO2L](n) (L = tridentate ONO Schiff base ligands based on the salicylidene-2-aminophenolato structure) have been synthesized and used as catalysts for the solvent-free epoxidation of olefins. The effect of donor (diethylamino) and/or acceptor (nitro) substituents has been studied.
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