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Article Dans Une Revue Chemical Communications Année : 2017

Alkali and alkaline earth metal ion binding by a foldamer capsule: selective recognition of magnesium hydrate

Résumé

Alkali and alkaline earth metal ion binding by an aromatic oligoamide foldamer was shown to induce its folding into a helical capsule. CD and NMR titrations revealed tight and selective binding of Mg 2+. Crystallographic studies demonstrated that, depending on the metal, binding may involve the first or second coordination spheres of the metal hydrates.
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hal-01831995 , version 1 (06-07-2018)

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Pedro Mateus, Barbara Wicher, Yann Ferrand, Ivan Huc. Alkali and alkaline earth metal ion binding by a foldamer capsule: selective recognition of magnesium hydrate. Chemical Communications, 2017, 53 (67), pp.9300-9303. ⟨10.1039/C7CC05422J⟩. ⟨hal-01831995⟩

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