C-1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2008

C-1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions

Résumé

One trumps two: Monosubstituted chiral bicyclo[2.2.2]octadiene ligands, derived from carvone, form complexes with rhodium to catalyze the asymmetric addition of boronic acid substrates to α,β-unsaturated ketones. The 1,4-adducts are produced in good yield and high enantioselectivity.

Domaines

Chimie organique

Dates et versions

hal-01722822 , version 1 (05-03-2018)

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Citer

Thomas Gendrineau, Olivier Chuzel, Hendrik Eijsberg, Jean-Pierre Genêt, Sylvain Darses. C-1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions. Angewandte Chemie International Edition, 2008, 47 (40), pp.7669 - 7672. ⟨10.1002/anie.200803230⟩. ⟨hal-01722822⟩

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