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Article Dans Une Revue Journal of Supercritical Fluids Année : 2017

Solubility and interfacial tension of thermoplastic polyurethane melt in supercritical carbon dioxide and nitrogen

J. Férec
G. Ausias
Y. Tirel
  • Fonction : Auteur
J. -M. Veille
  • Fonction : Auteur

Résumé

Various industries, such as automotive and leisure, show a great interest in foaming thermoplastic polyurethane (TPU) with physical blowing agents. Hence, this study aims to investigate the effects of absorption of carbon dioxide and nitrogen by melt TPU on solubility and interfacial tension. Using a pressure-volume-temperature apparatus for high pressure and temperature combined with a magnetic suspension balance, the solubility of carbon dioxide and nitrogen in thermoplastic polyurethane melt was measured at temperatures from 190 degrees C to 220 degrees C and at pressures to 25 MPa. The solubility of both super-critical fluids (SCF) in the TPU melt was then compared with semiempirical data and theoretical values calculated from the Sanchez-Lacombe equations of state (S-L EOS). The surface tension of the TPU/SCF interface was measured using the axisymmetric drop shape analysis profile. It was observed that the dependency of interfacial tension on temperature at high pressures decreases because of a reduction in SCF solubility at high temperatures. The relationship between the interfacial tension and the density difference of polymer-supercritical fluid was also examined using the generalized Macleod's equation. (C) 2016 Elsevier B.V. All rights reserved.
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Dates et versions

hal-01697237 , version 1 (31-01-2018)

Identifiants

Citer

A. Primel, J. Férec, G. Ausias, Y. Tirel, J. -M. Veille, et al.. Solubility and interfacial tension of thermoplastic polyurethane melt in supercritical carbon dioxide and nitrogen. Journal of Supercritical Fluids, 2017, 122, pp.52-57. ⟨10.1016/j.supflu.2016.11.016⟩. ⟨hal-01697237⟩
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