High spin to low spin relaxation regime change in a multistep 3D spin-crossover material - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2018

High spin to low spin relaxation regime change in a multistep 3D spin-crossover material

Résumé

The paper reports the study of the photoinduced high spin (HS) state lifetime in a multistep spin crossover compound. Despite the pronounced three-step transition of the [Fe(dpsme)Pt(CN)4]·2/3dpsme·xEtOH·yH2O {dpsme = 4,4′-di(pyridylthio)methane; EtOH = ethanol} 3D compound, neither the T(LIESST) nor the relaxation kinetics exhibits stepwise features. From the detailed investigation (experiments and simulations) of these relaxations and the observation of the light-induced thermal hysteresis, a phase transition around 58 K is suspected.
Fichier principal
Vignette du fichier
2018-021.pdf (1.56 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-01696992 , version 1 (30-01-2018)

Identifiants

Citer

Guillaume Chastanet, Natasha Sciortino, Suzanne Neville, Cameron Kepert. High spin to low spin relaxation regime change in a multistep 3D spin-crossover material. European Journal of Inorganic Chemistry, 2018, Molecular Magnetism, 2018 (3-4), pp.314-319. ⟨10.1002/ejic.201701127⟩. ⟨hal-01696992⟩
251 Consultations
55 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More